计算0.10mol/LHAc溶液的PH值
问题描述:
计算0.10mol/LHAc溶液的PH值
答
醋酸的电离常数Ka=1.8*10^-5
HAc Ac- + H+
Ka=1.8x10^-5 = [H+][Ac-] / (0.1-[H+]) = [H+]^2 / (0.1-[H+])
[H+]=0.00133 mol/L
pH= -lg[H+]= 2.88
答
先要查到:醋酸的电离常数Ka=1.8*10^-5,设电离的分子浓度为x
CH3COOHCH3COO- + H+
x x x
Ka=x^2/(0.1-x)=1.8*10^-5
由于c/Ka>500,所以可近似计算:x^2=0.1*1.8*10^-5即得x=1.34*10^-3
pH=2.87