有没有appreciate it when这种用法举个例子

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• 英语大神来分析句子结构,when+做什么成分,感觉怪怪的,居然有这种用法,大神举个例子,A little work when times are good is a big help when times are bad.
• I have never had 否定提前应该是什么?应该是Never have I had 还是 Never had I have?按理说应该是动词提前,所以应该是Never had I have,但我听到的却是Never have I had ,谁能从语法上解释一下吗?能举个例子就最好了.感谢两位回答，Easy5555说得很好，记句子是个好办法，但现在我就是记住句子了想再温习下语法，现在听的多语法生疏了。刚翻一下，本来倒装就是要把助动词提前的，呵呵，关键这种用法口语中不多见。
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• Gerstein said the superdelegate movement could give “cover” to other undecided delegates “who are nervous or on the fence or scared of crossing the Clintons,” in turn forcing the race to an end before June 3,when the final primaries are held.是不是in term的笔误?中文意思翻译为“从而”最合适,但是查不到in turn 有这个意思.是不是有这种用法?最好给个其它的例子.
• 有几个；1,氢氧化铁与硫酸钠为什么不会反应?那氢氧化钠与硫酸铁呢?那碳酸钠和硫酸铜呢?2,离子扩散时,比如Na+,是根据两边Na+的浓度差还是整个的液体密度差?举个例子,蒸馏水中有个半透膜,里面有胶体和氯化钠,那Na+浓度在这两个空间内是否相等呢?3,碘化银具有感光性,那银的卤化物有没有这种性质呢?
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• happen to dohappen to be doing happen to have done翻译下,还有没有其他的词语也能这样用,这种用法叫什么名字,再多举些例子
• 有没有appreciate it when这种用法举个例子
• one would expect 在句中的用法和作用是不是“理所当然”的意思?比如新概念里的一句课文.one would expect them to know their parts by heart翻译是：人们以为,这些演员一定会把台词记的很清楚.平时没有接触过one would expect 这个词,想知道这个在其它句型里怎么应用,最好举个例子,网上查到一句Usually,when one hears those words,one would expect the next words to be 'so I cannot comment.'翻出来是：通常情况下，当一个人听到此类言论时，接下来就会说“不予评论。反正总觉得这个词组平时和中文的说话习惯差很多，不知该怎么应用。
• Help sb. on something有这种用法吗?可否举个例子?
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• 英语翻译I sincerely do appreciate your kind gesture as to helping me out of this God forsaking camp where I am presently seeking political asylum as a refugee.我想知道 这里的 as to as to 在这里是个词组,还是分开的,如果当 至于 讲 那整句怎么翻