n(H3PO4):n(H2PO4-)=7:2,试求溶液中H+的浓度常温下,0.10mol/L的H3PO4(aq)中,N(H3PO4):N(H2PO4-)=7:2,试求溶液中H+的浓度

问题描述:

n(H3PO4):n(H2PO4-)=7:2,试求溶液中H+的浓度
常温下,0.10mol/L的H3PO4(aq)中,N(H3PO4):N(H2PO4-)=7:2,试求溶液中H+的浓度

根据题意:
N(H3PO4):N(H2PO4-)=7:2
N(H2PO4-)=0.1*2/(7+2)=0.022mol/l
N(H2PO4-)=N(H+)=0.022mol/l
溶液中H3PO4的电离远大于H2PO4-、HPO4^2-的电离,因此可以忽略二、三级电离.
参考资料:
K1=7.52×10-3(H3PO4电离常数)
K2=6.31×10-8 (H2PO4-电离常数)
K3=4.4×10-13 (HPO4^2-电离常数)