0.3000g MgO试样加入48.00ml盐酸(此盐酸1ml相当于0.01501g CaCO3)过量盐酸溶液用0.2000mol/LNaOH回滴,用去NaOH 4.30ml,求试样中MgO百分含量.( Mr(MgO)=40.30 Mr(C
问题描述:
0.3000g MgO试样加入48.00ml盐酸(此盐酸1ml相当于0.01501g CaCO3)过量盐酸溶液用0.2000mol/LNaOH回滴,用去NaOH 4.30ml,求试样中MgO百分含量.( Mr(MgO)=40.30 Mr(CaCO3)=100.1 )
答
盐酸的摩尔含量为:2*0.01501g/100.1g/mol*1000/l=0.2999mol/l
过量盐酸:0.2mol/l*4.3ml/1000=8.6×10-4mol
消耗盐酸:0.2999mol/l*48ml/1000-8.6×10-4=0.0135352mol
0.0135352/2*40.3=0.2727g
0.2727/0.3*100%=90.9%
试样中MgO百分含量为90.9%
式样中其他物质不与盐酸反应.