离域能,成键能,电子结合能的区别物化HMO部分的一个概念问题:Distinguish between delocalization energy,π-electron binding energy,and π-bond formation energy.离域能我大概知道是什么,也知道怎么算,可是另外两个我就搞不清楚也不知道怎么算了……求高人解答!
问题描述:
离域能,成键能,电子结合能的区别
物化HMO部分的一个概念问题:Distinguish between delocalization energy,π-electron binding energy,
and π-bond formation energy.离域能我大概知道是什么,也知道怎么算,可是另外两个我就搞不清楚也不知道怎么算了……求高人解答!
答
These are all terms originally associated with the Hückel approximation used in the treatment of conjugated π‐electron molecules,in which the π‐electrons are considered independent of the σ‐ele...