取1.43g Na2CO3•XH2O 溶于水配成10m L 溶液,然后逐滴滴入稀盐酸直至没有气体放出为止,用去盐酸 2.0m L,并收集到112m L CO2(标况). 计算: (1)稀盐酸物质的量浓度为_; (2)Na2CO3•xH2O的
问题描述:
取1.43g Na2CO3•XH2O 溶于水配成10m L 溶液,然后逐滴滴入稀盐酸直至没有气体放出为止,用去盐酸 2.0m L,并收集到112m L CO2(标况).
计算:
(1)稀盐酸物质的量浓度为______;
(2)Na2CO3•xH2O的摩尔质量______;
(3)x=______.
答
n(CO2)=
=0.005mol,0.112L 22.4L/mol
Na2CO3+2HCl=2NaCl+CO2↑+H2O
1 2 1
n(Na2CO3) n(HCl) 0.005mol
(1)n(HCl)=2×n(CO2)=2×0.005mol=0.01mol,
c(HCl)=
=5.0mol/L,0.01mol 0.002L
故答案为:5.0mol/L;
(2)n(Na2CO3•xH2O)=n(Na2CO3)=0.005mol,
M(Na2CO3•xH2O)=286g/mol,
故答案为:286g/mol;
(3)由摩尔质量可知:106+18x=286,x=10,
故答案为:10.