称取含FE(M=55.85)试样0.4000克,溶解后将其中的FE2+还原为fe2+,

问题描述:

称取含FE(M=55.85)试样0.4000克,溶解后将其中的FE2+还原为fe2+,
然后用浓度为0.02000MOL.L-1R K2CR2O7标淮溶液滴定,用去25.00ML.求FE2O3(Mr=159.7)的质量分数.

6Fe²+ + Cr₂O₇²+ + 14H+ = 6Fe³+ + 2Cr³+ + 7H₂O6 1x 0.02000*0.02500 = 0.0005000x = 6*0.0005000/1 = 0.003000 mol1 mol Fe2+相当于 0.5molFe2O3,0.003000 molFe2+相当于0....