VmLAl2(SO4)3溶液中含有Al3+mg,取V/2mL该溶液用水稀释至3VmL,则SO42-物质的量浓度

问题描述:

VmLAl2(SO4)3溶液中含有Al3+mg,取V/2mL该溶液用水稀释至3VmL,则SO42-物质的量浓度

n(Al3+) = mg/27g/mol = 0.037mol
c(Al3+) = 0.037mol /VmL = 37/V mol/L
则原溶液中硫酸根的浓度为:c(SO42-) = 3/2 *c(Al3+)
取一半原溶液稀释到3VmL,相当于把溶液稀释6倍,所以得到的硫酸的浓度:
c(SO42-) = 3/2 *c(Al3+) * 1/6 = 3/2 * 37/V mol/L * 1/6 = 37/4V mol/L额。。选择题里没有这个选项。。A;250m/27vB;25om/9vc;500m/9vD;125m/9vn(Al3+) = mg/27g/mol = m/27 molc(Al3+) = m/17mol /VmL = 1000m/27v mol/L则原溶液中硫酸根的浓度为:c(SO42-) = 3/2 *c(Al3+)取一半原溶液稀释到3VmL,相当于把溶液稀释6倍,所以得到的硫酸的浓度:c(SO42-) = 3/2 *c(Al3+) * 1/6 = 3/2 * 1000m/27v mol/L * 1/6 = 250m/27v mol/L 上面把铝离子的物质的量算错了,所以结果错了。谢谢提醒!