pH为多少时,25 ℃的HCN水溶液中,HCN形态占总氰浓度的90%?

问题描述:

pH为多少时,25 ℃的HCN水溶液中,HCN形态占总氰浓度的90%?

α=√Ka/c
c(HCN)=Ka/α^2=4.93×10^-10/0.01=4.93×10^-8
c(H+)=√Ka·c=√4.93^2×10^18=4.93×10^-9
PH=P(10^-7+4.93×10^-9)=6.98