铁离子与硫氰酸根离子反应为什么有三个方程式?即一个铁对应一个硫氰酸根····················· 两·······································三·················

问题描述:

铁离子与硫氰酸根离子反应为什么有三个方程式?
即一个铁对应一个硫氰酸根
····················· 两·················
······················三·················

铁离子与硫氰酸根离子反应最多可有6个方程式,这与二者的用量比有关.
中学一般用1∶3的这个反应来表示.
Fe3+ + SCN- = [Fe(SCN)]2+
Fe3+ + 2SCN- = [Fe(SCN)2]+
Fe3+ + 3SCN- = Fe(SCN)3
Fe3+ + 4SCN- = [Fe(SCN)4]-
Fe3+ + 5SCN- = [Fe(SCN)5]2-
Fe3+ + 6SCN- = [Fe(SCN)6]3-