已知100g CaCO3(S)分解生成CaO(S)和CO2(g)需要吸收178kJ热量,12gC(S)燃烧生成CO2(g)放出393.5kJ热量,如果把0.5t CaCO3煅烧成CaO(S),在理论上要用C(S)燃料多少kg?

问题描述:

已知100g CaCO3(S)分解生成CaO(S)和CO2(g)需要吸收178kJ热量,12gC(S)燃烧生成CO2(g)放出393.5kJ热量,如果把0.5t CaCO3煅烧成CaO(S),在理论上要用C(S)燃料多少kg?

0.5t 碳酸钙生成生石灰,依据热化学方程式计算可知吸收热量=0.5×106

178kJ
100g
=8.9×105kJ,
设理论上需焦炭x千克,
C(s)+O2(g)=CO2(g)△H2=-393.5kJ/mol
12g                        393.5kJ
x×1000                    8.9×105kJ
x=27.14kg,
答:0.5t 碳酸钙生成生石灰理论上需焦炭27.14kg.